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J Dent Res Dent Clin Dent Prospects. 2015;9(4): 226-232.
doi: 10.15171/joddd.2015.041
PMID: 26889359
PMCID: PMC4753031
  Abstract View: 1147
  PDF Download: 683

Original Research

Evaluation of Polymerization Efficacy in Composite Resins via FT-IR Spectroscopy and Vickers Microhardness Test

Tahereh-Sadat Jafarzadeh 1, Mohammad Erfan 2*, Marjan Behroozibakhsh 3, Mostafa Fatemi 3, Reza Masaeli 4, Yashar Rezaei 5, Hossein Bagheri 6, Yasaman Erfan 7

1 Associate Professor, Department of Dental Biomaterials, Tehran University of Medical Sciences, Iranian Tissue Bank and Research Center, Tehran Uni-versity of Medical Sciences Tehran, Iran
2 Associate Professor, Department of Pharmaceutics, School of Pharmacy, Shahid Bahashti University of Medical Sciences, Tehran, Iran
3 Assistant Professor, Research Center for Science and Technology in Medicine and Department of Dental Biomaterials, School of Dentistry, Tehran Uni-versity of Medical Sciences, Tehran, Iran
4 Ph.D Candidate, Research Center for Science and Technology in Medicine and Department of Dental Biomaterials, School of Dentistry, Tehran Univer-sity of Medical Sciences, Tehran, Iran
5 Assistant Professor, Department of Dental Biomaterials, Faculty of Dentistry, Tabriz University of Medical Sciences, Tabriz, Iran
6 Assistant Professor, Dental Materials Research Center, Faculty of Dentistry, Mashhad University of Medical Sciences, Mashhad, Iran
7 Dental Student, The International Branch of Shahid Behesti University of Medical Sciences and Health Services, Tehran, Iran
*Corresponding Author: Email: dr.hbagher6i@gmail.com

Abstract

Background and aims. Polymerization efficacy affects the properties and performance of composite resin restorations.The purpose of this study was to evaluate the effectiveness of polymerization of two micro-hybrid, two nano-hybrid and one nano-filled ormocer-based composite resins, cured by two different light-curing systems, using Fourier transformation infrared (FT-IR) spectroscopy and Vickers microhardness testing at two different depths (top surface, 2 mm).Materials and methods. For FT-IR spectrometry, five cylindrical specimens (5mm in diameter × 2 mm in length) were prepared from each composite resin using Teflon molds and polymerized for 20 seconds. Then, 70-μm wafers were sectioned at the top surface and at2mm from the top surface. The degree of conversion for each sample was calculated using FT-IR spectroscopy. For Vickers micro-hardness testing, three cylindrical specimens were prepared from each composite resin and polymerized for 20 seconds. The Vickers microhardness test (Shimadzu, Type M, Japan) was performed at the top and bottom (depth=2 mm) surfaces of each specimen. Three-way ANOVA with independent variables and Tukey tests were performed at 95% significance level.Results. No significant differences were detected in degree of conversion and microhardness between LED and QTH light-curing units except for the ormocer-based specimen, CeramX, which exhibited significantly higher DC by LED. All the composite resins showed a significantly higher degree of conversion at the surface. Microhardness was not significantly affected by depth, except for Herculite XRV Ultra and CeramX, which showed higher values at the surface.Conclusion. Composite resins containing nano-particles generally exhibited more variations in degree of conversion and microhardness.
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Submitted: 19 Jan 2016
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